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Direct measurement of the energy thresholds to conformational isomerization in Tryptamine: Experiment and theory

Clarkson, JR and Dian, BC and Moriggi, L and Defusco, A and McCarthy, V and Jordan, KD and Zwier, TS (2005) Direct measurement of the energy thresholds to conformational isomerization in Tryptamine: Experiment and theory. Journal of Chemical Physics, 122 (21). ISSN 0021-9606

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Abstract

The methods of stimulated emission pumping-hole spectroscopy (SEP-HFS) and stimulated emission pumping population transfer spectroscopy (SEP-PTS) were applied to the conformation-specific study of conformational isomerization in tryptamine. The methods employ stimulated emission pumping to selectively excite a fraction of the population of a single conformation of TRA to well-defined ground-state vibration levels. The method uses collisions as an integral part of the experimental scheme. Hole-filling methods can also be applied to the study of isomerization in a much wider range of contexts.


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Details

Item Type: Article
Status: Published
Creators/Authors:
CreatorsEmailPitt UsernameORCID
Clarkson, JR
Dian, BC
Moriggi, L
Defusco, A
McCarthy, V
Jordan, KDjordan@pitt.eduJORDAN
Zwier, TS
Date: 1 June 2005
Date Type: Publication
Journal or Publication Title: Journal of Chemical Physics
Volume: 122
Number: 21
DOI or Unique Handle: 10.1063/1.1924454
Schools and Programs: Dietrich School of Arts and Sciences > Chemistry
Refereed: Yes
ISSN: 0021-9606
PubMed ID: 15974742
Date Deposited: 29 Oct 2012 21:26
Last Modified: 02 Feb 2019 15:56
URI: http://d-scholarship.pitt.edu/id/eprint/16070

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