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Organocatalysis and C-H activation meet radical- and electron-transfer reactions

Studer, A and Curran, DP (2011) Organocatalysis and C-H activation meet radical- and electron-transfer reactions. Angewandte Chemie - International Edition, 50 (22). 5018 - 5022. ISSN 1433-7851

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A radical outlook: Recently published "organocatalytic C-H activation reactions" have now been interpreted as base-promoted homolytic substitutions. The addition of an aryl radical to an arene followed by deprotonation (see above) and electron transfer form part of the chain reaction. Although these new results are not conceptual breakthroughs, they could be experimental breakthroughs because they presage new transformations in radical (anion) chemistry. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.


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Item Type: Article
Status: Published
CreatorsEmailPitt UsernameORCID
Studer, A
Curran, DPcurran@pitt.eduCURRAN
Date: 23 May 2011
Date Type: Publication
Journal or Publication Title: Angewandte Chemie - International Edition
Volume: 50
Number: 22
Page Range: 5018 - 5022
DOI or Unique Handle: 10.1002/anie.201101597
Schools and Programs: Dietrich School of Arts and Sciences > Chemistry
Refereed: Yes
ISSN: 1433-7851
PubMed ID: 21523871
Date Deposited: 24 Jan 2013 20:49
Last Modified: 02 Feb 2019 15:58


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