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Generation and reactions of an unsubstituted n-heterocyclic carbene boryl anion

Monot, J and Solovyev, A and Bonin-Dubarle, H and Derat, E and Curran, DP and Robert, M and Fensterbank, L and Malacria, M and Lacôte, E (2010) Generation and reactions of an unsubstituted n-heterocyclic carbene boryl anion. Angewandte Chemie - International Edition, 49 (48). 9166 - 9169. ISSN 1433-7851

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Abstract

Lying low: A lithiated unsubstituted N-heterocyclic carbene (NHC) boryl anion can be generated by reduction, and trapped by electrophiles (see scheme; dipp=2,6-diisopropylphenyl) to provide new substituted NHC boranes. It is yet another example of a low-valent boron compound or boron-containing reactive intermediate stabilized by an NHC, thereby extending the scope of NHC borane chemistry. Copyright © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.


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Details

Item Type: Article
Status: Published
Creators/Authors:
CreatorsEmailPitt UsernameORCID
Monot, J
Solovyev, A
Bonin-Dubarle, H
Derat, E
Curran, DPcurran@pitt.eduCURRAN
Robert, M
Fensterbank, L
Malacria, M
Lacôte, E
Date: 22 November 2010
Date Type: Publication
Journal or Publication Title: Angewandte Chemie - International Edition
Volume: 49
Number: 48
Page Range: 9166 - 9169
DOI or Unique Handle: 10.1002/anie.201004215
Schools and Programs: Dietrich School of Arts and Sciences > Chemistry
Refereed: Yes
ISSN: 1433-7851
PubMed ID: 20853388
Date Deposited: 08 Feb 2013 21:09
Last Modified: 02 Feb 2019 15:58
URI: http://d-scholarship.pitt.edu/id/eprint/17237

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