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Preparation of NHC borane complexes by lewis base exchange with amine- and phosphine-boranes

Brahmi, MM and Monot, J and Desage-El Murr, M and Curran, DP and Fensterbank, L and Lacôte, E and Malacria, M (2010) Preparation of NHC borane complexes by lewis base exchange with amine- and phosphine-boranes. Journal of Organic Chemistry, 75 (20). 6983 - 6985. ISSN 0022-3263

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A versatile new method for the preparation of NHC boranes starting from two stable, readily available reactants-an heterocyclic salt and an amine or phosphine-borane-is reported. It uses a Lewis base exchange at boron and provides easy access to new NHC boranes, in particular B-substituted borane ones. © 2010 American Chemical Society.


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Item Type: Article
Status: Published
CreatorsEmailPitt UsernameORCID
Brahmi, MM
Monot, J
Desage-El Murr, M
Curran, DPcurran@pitt.eduCURRAN
Fensterbank, L
Lacôte, E
Malacria, M
Date: 15 October 2010
Date Type: Publication
Journal or Publication Title: Journal of Organic Chemistry
Volume: 75
Number: 20
Page Range: 6983 - 6985
DOI or Unique Handle: 10.1021/jo101301d
Schools and Programs: Dietrich School of Arts and Sciences > Chemistry
Refereed: Yes
ISSN: 0022-3263
MeSH Headings: Amines--chemistry; Boranes--chemical synthesis; Boranes--chemistry; Heterocyclic Compounds--chemical synthesis; Heterocyclic Compounds--chemistry; Methane--analogs & derivatives; Methane--chemical synthesis; Methane--chemistry; Molecular Structure; Phosphines--chemistry; Stereoisomerism
PubMed ID: 20839823
Date Deposited: 08 Feb 2013 21:00
Last Modified: 02 Feb 2019 15:58


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