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Radical deoxygenation of xanthates and related functional groups with new minimalist N-heterocyclic carbene boranes

Ueng, SH and Fensterbank, L and Lacôte, E and Malacria, M and Curran, DP (2010) Radical deoxygenation of xanthates and related functional groups with new minimalist N-heterocyclic carbene boranes. Organic Letters, 12 (13). 3002 - 3005. ISSN 1523-7060

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Abstract

Minimalist N-heterocyclic carbene boranes 1,3-dimethylimidazol-2- ylideneborane and 2,4-dimethyl-1,2,4-triazol-3-ylideneborane are readily available and have low molecular weights. They exhibit superior performance to first-generation NHC-boranes, providing improved yields in reductions of xanthates and related functional groups. © 2010 American Chemical Society.


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Details

Item Type: Article
Status: Published
Creators/Authors:
CreatorsEmailPitt UsernameORCID
Ueng, SH
Fensterbank, L
Lacôte, E
Malacria, M
Curran, DPcurran@pitt.eduCURRAN
Date: 2 July 2010
Date Type: Publication
Journal or Publication Title: Organic Letters
Volume: 12
Number: 13
Page Range: 3002 - 3005
DOI or Unique Handle: 10.1021/ol101015m
Schools and Programs: Dietrich School of Arts and Sciences > Chemistry
Refereed: Yes
ISSN: 1523-7060
MeSH Headings: Boranes--chemistry; Free Radicals--chemistry; Heterocyclic Compounds--chemistry; Methane--analogs & derivatives; Methane--chemistry; Molecular Structure; Molecular Weight; Oxygen--chemistry; Stereoisomerism; Thiones--chemistry
PubMed ID: 20536159
Date Deposited: 08 Feb 2013 20:45
Last Modified: 02 Feb 2019 15:58
URI: http://d-scholarship.pitt.edu/id/eprint/17301

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