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Enantioselective -chlorination of aldehydes with recyclable fluorous (s)-pyrrolidine-thiourea bifunctional organocatalyst

Wang, L and Cai, C and Curran, DP and Zhang, W (2010) Enantioselective -chlorination of aldehydes with recyclable fluorous (s)-pyrrolidine-thiourea bifunctional organocatalyst. Synlett (3). 433 - 436. ISSN 0936-5214

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A novel fluorous (S)-pyrrolidine-thiourea bifunctional organocatalyst is prepared. The catalyst shows good activity and enantioselectivity for direct -chlorination of aldehydes using N-chlorosuccinimide (NCS) as the chlorine source. It can be recovered from the reaction mixture by fluorous solid-phase extraction with excellent purity for direct reuse. © Georg Thieme Verlag Stuttgart · New York.


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Item Type: Article
Status: Published
CreatorsEmailPitt UsernameORCID
Wang, L
Cai, C
Curran, DPcurran@pitt.eduCURRAN
Zhang, W
Date: 15 February 2010
Date Type: Publication
Journal or Publication Title: Synlett
Number: 3
Page Range: 433 - 436
DOI or Unique Handle: 10.1055/s-0029-1219198
Schools and Programs: Dietrich School of Arts and Sciences > Chemistry
Refereed: Yes
ISSN: 0936-5214
PubMed Central ID: PMC2922060
PubMed ID: 20717504
Date Deposited: 14 Feb 2013 21:15
Last Modified: 01 Mar 2019 14:55


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