Monot, J and Makhlourbrahmi, M and Ueng, SH and Robert, C and Murr, MDEI and Curran, DP and Malacria, M and Fensterbank, L and Lacôte, E
(2009)
Suzuki-miyaura coupling of NHC-Boranes: A new addition to the C-C coupling toolbox.
Organic Letters, 11 (21).
4914 - 4917.
ISSN 1523-7060
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Abstract
Complexes of triaryl- and trialkylboranes with N-heterocyclic carbenes (NHCs) participate In Suzuki-Miyaura cross-coupling reactions and provide coupled products In good yields under base-free conditions. The reaction can be applied to Csp2-Csp2 and Csp2-Csp3 carbon-carbon bond formation with triflates, iodides, bromides, and chlorides. These results enrich the utility of NHC-borane complexes, which can be added to the toolkit of Suzukl-Miyaura cross-couplings, along with boronlc acids and organotrlfluoroborates. © 2009 American Chemical Society.
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