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Suzuki-miyaura coupling of NHC-Boranes: A new addition to the C-C coupling toolbox

Monot, J and Makhlourbrahmi, M and Ueng, SH and Robert, C and Murr, MDEI and Curran, DP and Malacria, M and Fensterbank, L and Lacôte, E (2009) Suzuki-miyaura coupling of NHC-Boranes: A new addition to the C-C coupling toolbox. Organic Letters, 11 (21). 4914 - 4917. ISSN 1523-7060

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Complexes of triaryl- and trialkylboranes with N-heterocyclic carbenes (NHCs) participate In Suzuki-Miyaura cross-coupling reactions and provide coupled products In good yields under base-free conditions. The reaction can be applied to Csp2-Csp2 and Csp2-Csp3 carbon-carbon bond formation with triflates, iodides, bromides, and chlorides. These results enrich the utility of NHC-borane complexes, which can be added to the toolkit of Suzukl-Miyaura cross-couplings, along with boronlc acids and organotrlfluoroborates. © 2009 American Chemical Society.


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Item Type: Article
Status: Published
CreatorsEmailPitt UsernameORCID
Monot, J
Makhlourbrahmi, M
Ueng, SH
Robert, C
Murr, MDEI
Curran, DPcurran@pitt.eduCURRAN
Malacria, M
Fensterbank, L
Lacôte, E
Date: 5 November 2009
Date Type: Publication
Journal or Publication Title: Organic Letters
Volume: 11
Number: 21
Page Range: 4914 - 4917
DOI or Unique Handle: 10.1021/ol902012c
Schools and Programs: Dietrich School of Arts and Sciences > Chemistry
Refereed: Yes
ISSN: 1523-7060
PubMed ID: 19799407
Date Deposited: 18 Feb 2013 15:34
Last Modified: 22 Jun 2021 12:56


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