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N-heterocyclic carbene-catalyzed hydrosilylation of styryl and propargylic alcohols with dihydrosilanes

Zhao, Q and Curran, DP and Malacria, M and Fensterbank, L and Goddard, JP and Lacôte, E (2011) N-heterocyclic carbene-catalyzed hydrosilylation of styryl and propargylic alcohols with dihydrosilanes. Chemistry - A European Journal, 17 (36). 9911 - 9914. ISSN 0947-6539

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Abstract

Reducing alkenes to tears: Addition of structurally diverse N-heterocyclic carbenes (NHCs) to silicon allows the reduction of propargylic and styryl alcohols through an organocatalyzed silylation/direct hydride transfer tandem reaction (see scheme). Catalytic turnover is enabled by the switch to and from hypervalent silicon. This provides a new synthetic application of NHC-main group element complexes. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.


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Details

Item Type: Article
Status: Published
Creators/Authors:
CreatorsEmailPitt UsernameORCID
Zhao, Q
Curran, DPcurran@pitt.eduCURRAN
Malacria, M
Fensterbank, L
Goddard, JP
Lacôte, E
Date: 29 August 2011
Date Type: Publication
Journal or Publication Title: Chemistry - A European Journal
Volume: 17
Number: 36
Page Range: 9911 - 9914
DOI or Unique Handle: 10.1002/chem.201101822
Schools and Programs: Dietrich School of Arts and Sciences > Chemistry
Refereed: Yes
ISSN: 0947-6539
PubMed ID: 21796697
Date Deposited: 14 Mar 2013 14:12
Last Modified: 02 Feb 2019 15:59
URI: http://d-scholarship.pitt.edu/id/eprint/17714

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