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The parent borylene: Betwixt and between

Curran, DP and Boussonnière, A and Geib, SJ and Lacôte, E (2012) The parent borylene: Betwixt and between. Angewandte Chemie - International Edition, 51 (7). 1602 - 1605. ISSN 1433-7851

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Still elusive: The reduction of dimethylimidazol-2-ylidene dichloroborane by sodium naphthalenide has been suggested to provide a borylene that cycloadds to naphthalene to make a borirane. Evidence has been provided that this borirane instead arises from coupling of a boryl radical and sodium naphthalenide. In contrast, reduction of 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene dichloroborane and the related dimesityl derivative provide novel C-H insertion products that may have arisen from a borylene. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.


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Item Type: Article
Status: Published
CreatorsEmailPitt UsernameORCID
Curran, DPcurran@pitt.eduCURRAN
Boussonnière, A
Geib, SJgeib@pitt.eduGEIB0000-0002-9160-7857
Lacôte, E
Date: 13 February 2012
Date Type: Publication
Journal or Publication Title: Angewandte Chemie - International Edition
Volume: 51
Number: 7
Page Range: 1602 - 1605
DOI or Unique Handle: 10.1002/anie.201107238
Schools and Programs: Dietrich School of Arts and Sciences > Chemistry
Refereed: Yes
ISSN: 1433-7851
MeSH Headings: Boron Compounds--chemical synthesis; Boron Compounds--chemistry; Crystallography, X-Ray; Models, Molecular; Molecular Structure
PubMed ID: 22311810
Date Deposited: 29 Mar 2013 16:16
Last Modified: 02 Feb 2019 15:58


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