Curran, DP and Boussonnière, A and Geib, SJ and Lacôte, E
(2012)
The parent borylene: Betwixt and between.
Angewandte Chemie - International Edition, 51 (7).
1602 - 1605.
ISSN 1433-7851
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Abstract
Still elusive: The reduction of dimethylimidazol-2-ylidene dichloroborane by sodium naphthalenide has been suggested to provide a borylene that cycloadds to naphthalene to make a borirane. Evidence has been provided that this borirane instead arises from coupling of a boryl radical and sodium naphthalenide. In contrast, reduction of 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene dichloroborane and the related dimesityl derivative provide novel C-H insertion products that may have arisen from a borylene. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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Details
| Item Type: |
Article
|
| Status: |
Published |
| Creators/Authors: |
|
| Date: |
13 February 2012 |
| Date Type: |
Publication |
| Journal or Publication Title: |
Angewandte Chemie - International Edition |
| Volume: |
51 |
| Number: |
7 |
| Page Range: |
1602 - 1605 |
| DOI or Unique Handle: |
10.1002/anie.201107238 |
| Schools and Programs: |
Dietrich School of Arts and Sciences > Chemistry |
| Refereed: |
Yes |
| ISSN: |
1433-7851 |
| MeSH Headings: |
Boron Compounds--chemical synthesis; Boron Compounds--chemistry; Crystallography, X-Ray; Models, Molecular; Molecular Structure |
| PubMed ID: |
22311810 |
| Date Deposited: |
29 Mar 2013 16:16 |
| Last Modified: |
02 Feb 2019 15:58 |
| URI: |
http://d-scholarship.pitt.edu/id/eprint/17968 |
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