Link to the University of Pittsburgh Homepage
Link to the University Library System Homepage Link to the Contact Us Form

Isolating the charge-transfer component of the anionic H bond via spin suppression of the intracluster proton transfer reaction in the NO<sup>-</sup>·H<inf>2</inf>O entrance channel complex

Robertson, WH and Johnson, MA and Myshakin, EM and Jordan, KD (2002) Isolating the charge-transfer component of the anionic H bond via spin suppression of the intracluster proton transfer reaction in the NO<sup>-</sup>·H<inf>2</inf>O entrance channel complex. Journal of Physical Chemistry A, 106 (42). 10010 - 10014. ISSN 1089-5639

[img] Plain Text (licence)
Available under License : See the attached license file.

Download (1kB)

Abstract

We report the vibrational predissociation spectrum of the NO-·H2O complex in the OH stretching region. The ionic H-bonded OH stretch is much less red-shifted and less structured in the vibrational spectrum of NO-·H2O than in that of the O2-·H2O cluster, despite the larger proton affinity of NO- relative to O2-. It is argued that the differences between the spectra of these two species are primarily a consequence of the greater charge-transfer character in the O2-·H2O cluster and that the charge-transfer component is much less important in NO-·H2O because of its triplet spin character.


Share

Citation/Export:
Social Networking:
Share |

Details

Item Type: Article
Status: Published
Creators/Authors:
CreatorsEmailPitt UsernameORCID
Robertson, WH
Johnson, MA
Myshakin, EM
Jordan, KDjordan@pitt.eduJORDAN
Date: 24 October 2002
Date Type: Publication
Journal or Publication Title: Journal of Physical Chemistry A
Volume: 106
Number: 42
Page Range: 10010 - 10014
DOI or Unique Handle: 10.1021/jp020891s
Schools and Programs: Dietrich School of Arts and Sciences > Chemistry
Refereed: Yes
ISSN: 1089-5639
Date Deposited: 29 Mar 2013 16:31
Last Modified: 02 Feb 2019 15:56
URI: http://d-scholarship.pitt.edu/id/eprint/17970

Metrics

Monthly Views for the past 3 years

Plum Analytics

Altmetric.com


Actions (login required)

View Item View Item