Myshakin, EM and Jordan, KD and Robertson, WH and Weddle, GH and Johnson, MA
(2003)
Dominant structural motifs of NO<sup>-</sup>·(H<inf>2</inf>O)<inf>n</inf> complexes: Infrared spectroscopic and ab initio studies.
Journal of Chemical Physics, 118 (11).
4945 - 4953.
ISSN 0021-9606
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Abstract
Infrared spectra of the NO-·(H2O)n=1-5 clusters are obtained by argon predissociation spectroscopy. Thus, the spectrum of NO-·H2O revealed a free OH band and two intense red-shifted IHB bands, consistent with two asymmetric isomers with single H-bonded Cs structures. The NO- anion favors the formation of cyclic hydrates in contrast to O2-, which encourages more open hydration motifs.
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