Dominant structural motifs of NO^-·(H<inf>2</inf>O)<inf>n</inf> complexes: Infrared spectroscopic and ab initio studies

Myshakin, EM and Jordan, KD and Robertson, WH and Weddle, GH and Johnson, MA (2003) Dominant structural motifs of NO^-·(H<inf>2</inf>O)<inf>n</inf> complexes: Infrared spectroscopic and ab initio studies. Journal of Chemical Physics, 118 (11). 4945 - 4953. ISSN 0021-9606

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Abstract

Infrared spectra of the NO-·(H2O)n=1-5 clusters are obtained by argon predissociation spectroscopy. Thus, the spectrum of NO-·H2O revealed a free OH band and two intense red-shifted IHB bands, consistent with two asymmetric isomers with single H-bonded Cs structures. The NO- anion favors the formation of cyclic hydrates in contrast to O2-, which encourages more open hydration motifs.

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Details

Item Type:	Article
Status:	Published
Creators/Authors:	Creators Email Pitt Username ORCID Myshakin, EM Jordan, KD jordan@pitt.edu JORDAN Robertson, WH Weddle, GH Johnson, MA
Date:	15 March 2003
Date Type:	Publication
Journal or Publication Title:	Journal of Chemical Physics
Volume:	118
Number:	11
Page Range:	4945 - 4953
DOI or Unique Handle:	10.1063/1.1545771
Schools and Programs:	Dietrich School of Arts and Sciences > Chemistry
Refereed:	Yes
ISSN:	0021-9606
Date Deposited:	08 Apr 2013 17:33
Last Modified:	22 Jun 2021 12:55
URI:	http://d-scholarship.pitt.edu/id/eprint/17997

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