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Dominant structural motifs of NO<sup>-</sup>·(H<inf>2</inf>O)<inf>n</inf> complexes: Infrared spectroscopic and ab initio studies

Myshakin, EM and Jordan, KD and Robertson, WH and Weddle, GH and Johnson, MA (2003) Dominant structural motifs of NO<sup>-</sup>·(H<inf>2</inf>O)<inf>n</inf> complexes: Infrared spectroscopic and ab initio studies. Journal of Chemical Physics, 118 (11). 4945 - 4953. ISSN 0021-9606

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Abstract

Infrared spectra of the NO-·(H2O)n=1-5 clusters are obtained by argon predissociation spectroscopy. Thus, the spectrum of NO-·H2O revealed a free OH band and two intense red-shifted IHB bands, consistent with two asymmetric isomers with single H-bonded Cs structures. The NO- anion favors the formation of cyclic hydrates in contrast to O2-, which encourages more open hydration motifs.


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Details

Item Type: Article
Status: Published
Creators/Authors:
CreatorsEmailPitt UsernameORCID
Myshakin, EM
Jordan, KDjordan@pitt.eduJORDAN
Robertson, WH
Weddle, GH
Johnson, MA
Date: 15 March 2003
Date Type: Publication
Journal or Publication Title: Journal of Chemical Physics
Volume: 118
Number: 11
Page Range: 4945 - 4953
DOI or Unique Handle: 10.1063/1.1545771
Schools and Programs: Dietrich School of Arts and Sciences > Chemistry
Refereed: Yes
ISSN: 0021-9606
Date Deposited: 08 Apr 2013 17:33
Last Modified: 02 Feb 2019 15:56
URI: http://d-scholarship.pitt.edu/id/eprint/17997

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