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Dipole-bound anions of highly polar molecules: Ethylene carbonate and vinylene carbonate

Hammer, NI and Hinde, RJ and Compton, RN and Diri, K and Jordan, KD and Radisic, D and Stokes, ST and Bowen, KH (2004) Dipole-bound anions of highly polar molecules: Ethylene carbonate and vinylene carbonate. Journal of Chemical Physics, 120 (2). 685 - 690. ISSN 0021-9606

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Narrow intense resonances in the photodetachment spectra of the valence-bound anions of several polar molecules were observed. The experiments showed that molecules which support valence-bound anion states may also exhibit features characteristic of dipole-bound anions. This paper considers the diabatic coupling terms between dipole-bound and valence-bound negative ion states of nitromethane.


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Item Type: Article
Status: Published
CreatorsEmailPitt UsernameORCID
Hammer, NI
Hinde, RJ
Compton, RN
Diri, K
Jordan, KDjordan@pitt.eduJORDAN
Radisic, D
Stokes, ST
Bowen, KH
Date: 8 January 2004
Date Type: Publication
Journal or Publication Title: Journal of Chemical Physics
Volume: 120
Number: 2
Page Range: 685 - 690
DOI or Unique Handle: 10.1063/1.1629669
Schools and Programs: Dietrich School of Arts and Sciences > Chemistry
Refereed: Yes
ISSN: 0021-9606
PubMed ID: 15267903
Date Deposited: 08 Apr 2013 17:31
Last Modified: 19 Jan 2019 14:55


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