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Dipole-bound anions of carbonyl, nitrile, and sulfoxide containing molecules

Hammer, NI and Diri, K and Jordan, KD and Desfrançois, C and Compton, RN (2003) Dipole-bound anions of carbonyl, nitrile, and sulfoxide containing molecules. Journal of Chemical Physics, 119 (7). 3650 - 3660. ISSN 0021-9606

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Abstract

A study was performed on dipole-bound anions of 27 molecules containing either a carbonyl, sulfoxide or nitrile group. Rydberg electron transfer (RET) reactions with rubidium atoms excited to ns2S and nd2D excited states were used for the purpose. The dependencies of the electron affinity upon dipole moment, dispersion interaction, polarizability, conformation and geometry of the molecules were also investigated.


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Details

Item Type: Article
Status: Published
Creators/Authors:
CreatorsEmailPitt UsernameORCID
Hammer, NI
Diri, K
Jordan, KDjordan@pitt.eduJORDAN
Desfrançois, C
Compton, RN
Date: 15 August 2003
Date Type: Publication
Journal or Publication Title: Journal of Chemical Physics
Volume: 119
Number: 7
Page Range: 3650 - 3660
DOI or Unique Handle: 10.1063/1.1590959
Schools and Programs: Dietrich School of Arts and Sciences > Chemistry
Refereed: Yes
ISSN: 0021-9606
Date Deposited: 08 Apr 2013 17:18
Last Modified: 02 Feb 2019 15:56
URI: http://d-scholarship.pitt.edu/id/eprint/18073

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