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Fluorous "racemic" mixture synthesis: Polysaccharide-based chiral columns for simultaneous demix and enantioseparation of racemic fluorous tagged compounds

Tonoi, T and Zhang, W and Curran, DP and Mikami, K (2008) Fluorous "racemic" mixture synthesis: Polysaccharide-based chiral columns for simultaneous demix and enantioseparation of racemic fluorous tagged compounds. Chirality, 20 (3-4). 597 - 603. ISSN 0899-0042

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Abstract

The proof of concept experiments of fluorous "racemic" mixture synthesis (FRMS) is shown using polysaccharide-based chiral stationary phases. The mixture of racemic O-benzoylmandelate derivatives bearing different lengths of fluorous cleavable tags undergoes sequential reactions to provide individual derivatives as well as their enantiomers resolved on polysaccharide-based chiral HPLC columns (DAICEL CHIRALCEL® and CHIRALPAK® series). © 2008 Wiley-Liss, Inc.


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Details

Item Type: Article
Status: Published
Creators/Authors:
CreatorsEmailPitt UsernameORCID
Tonoi, T
Zhang, W
Curran, DPcurran@pitt.eduCURRAN
Mikami, K
Date: 3 March 2008
Date Type: Publication
Journal or Publication Title: Chirality
Volume: 20
Number: 3-4
Page Range: 597 - 603
DOI or Unique Handle: 10.1002/chir.20487
Schools and Programs: Dietrich School of Arts and Sciences > Chemistry
Refereed: Yes
ISSN: 0899-0042
MeSH Headings: Chromatography, High Pressure Liquid--methods; Fluorine--chemistry; Magnetic Resonance Spectroscopy; Mandelic Acids--chemical synthesis; Mandelic Acids--chemistry; Mandelic Acids--isolation & purification; Polysaccharides; Stereoisomerism
PubMed ID: 18205199
Date Deposited: 08 Apr 2013 17:20
Last Modified: 02 Feb 2019 15:58
URI: http://d-scholarship.pitt.edu/id/eprint/18119

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