Curran, DP and Keller, AI
(2006)
Radical additions of aryl iodides to arenes are facilitated by oxidative rearomatization with dioxygen.
Journal of the American Chemical Society, 128 (42).
13706 - 13707.
ISSN 0002-7863
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Abstract
Inter- and intramolecular additions of aryl radicals derived from aryl iodides to arenes are promoted by tris(trimethylsilyl)silane and occur under exceptionally mild conditions (15-30 min at 25 °C) in nondegassed benzene. A chain mechanism involving reaction of the intermediate cyclohexadienyl radical with oxygen to directly generate the aromatized product and the hydroperoxy radical is proposed. Copyright © 2006 American Chemical Society.
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