Curran, DP and Ogoe, C
(2006)
A new fluorous methoxymethyl (<sup>F</sup>MOM) protecting group for alcohols.
QSAR and Combinatorial Science, 25 (8-9).
732 - 735.
ISSN 1611-020X
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Abstract
A new fluorous analogue of the popular MOM (methoxymethyl) protecting group can be introduced by reactions of alcohols with 1H,1H,2H,2H,3H,3H- perfluoroundecyloxymethyl chloride (C8F17(CH 2)3OCH2Cl) and the resulting fluorous methoxymethyl (FMOM) adducts can be deprotected under Brønsted or Lewis acidic conditions. The results suggest that the FMOM protecting group will find use in a number of fluorous synthesis settings. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.
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