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Contribution of a solute's chiral solvent imprint to optical rotation

Mukhopadhyay, P and Zuber, G and Wipf, P and Beratan, DN (2007) Contribution of a solute's chiral solvent imprint to optical rotation. Angewandte Chemie - International Edition, 46 (34). 6450 - 6452. ISSN 1433-7851

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Solvent or solute dissymmetry? The dissymmetric ordering of solvent molecules around the chiral solute (see picture) contributes to the chiroptical signature. Indeed, the solvent can dominate the chiroptical response, as shown for (S)-methyloxirane in benzene. (Figure Presented). © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.


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Item Type: Article
Status: Published
CreatorsEmailPitt UsernameORCID
Mukhopadhyay, P
Zuber, G
Wipf, Ppwipf@pitt.eduPWIPF
Beratan, DN
Date: 5 September 2007
Date Type: Publication
Journal or Publication Title: Angewandte Chemie - International Edition
Volume: 46
Number: 34
Page Range: 6450 - 6452
DOI or Unique Handle: 10.1002/anie.200702273
Schools and Programs: Dietrich School of Arts and Sciences > Chemistry
Refereed: Yes
ISSN: 1433-7851
PubMed ID: 17645276
Date Deposited: 07 Aug 2013 15:43
Last Modified: 02 Feb 2019 15:57


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