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Synthesis, reaction, and recycle of light fluorous Grubbs-Hoveyda catalysts for alkene metathesis

Matsugi, M and Curran, DP (2005) Synthesis, reaction, and recycle of light fluorous Grubbs-Hoveyda catalysts for alkene metathesis. Journal of Organic Chemistry, 70 (5). 1636 - 1642. ISSN 0022-3263

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Abstract

(Chemical Equation Presented) Light fluorous versions of first- and second-generation Grubbs-Hoveyda metathesis catalysts are introduced. These exhibit the expected reactivity profile, are readily recovered from reaction mixtures by fluorous solid-phase extraction, and can be routinely reused five or more times. The catalysts can be used in a stand alone fashion, or supported on fluorous silica gel. © 2005 American Chemical Society.


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Details

Item Type: Article
Status: Published
Creators/Authors:
CreatorsEmailPitt UsernameORCID
Matsugi, M
Curran, DPcurran@pitt.eduCURRAN
Date: 4 March 2005
Date Type: Publication
Journal or Publication Title: Journal of Organic Chemistry
Volume: 70
Number: 5
Page Range: 1636 - 1642
DOI or Unique Handle: 10.1021/jo048001n
Schools and Programs: Dietrich School of Arts and Sciences > Chemistry
Refereed: Yes
ISSN: 0022-3263
MeSH Headings: Alkenes--chemical synthesis; Alkenes--chemistry; Catalysis; Fluorides--chemistry; Molecular Structure; Organometallic Compounds--chemical synthesis; Organometallic Compounds--chemistry; Ruthenium--chemistry
PubMed ID: 15730282
Date Deposited: 07 Aug 2013 14:47
Last Modified: 02 Feb 2019 15:59
URI: http://d-scholarship.pitt.edu/id/eprint/19529

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