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Radical cyclization approach to spirocyclohexadienones

González-López De Turiso, F and Curran, DP (2005) Radical cyclization approach to spirocyclohexadienones. Organic Letters, 7 (1). 151 - 154. ISSN 1523-7060

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(Chemical Equation Presented) Cyclization of an aryl radical at the ipso position of a p-O-aryl-substituted acetamide or benzamide generates oxindoles or quinolones bearing spirocyclohexadienone rings. This versatile reaction is applied to formal syntheses of the vasopressin inhibitor SR121463A and aza-galanthamine.


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Item Type: Article
Status: Published
CreatorsEmailPitt UsernameORCID
González-López De Turiso, F
Curran, DPcurran@pitt.eduCURRAN
Date: 6 January 2005
Date Type: Publication
Journal or Publication Title: Organic Letters
Volume: 7
Number: 1
Page Range: 151 - 154
DOI or Unique Handle: 10.1021/ol0477226
Schools and Programs: Dietrich School of Arts and Sciences > Chemistry
Refereed: Yes
ISSN: 1523-7060
MeSH Headings: Cyclization; Cyclohexanes--chemistry; Cyclohexenes; Spiro Compounds--chemistry
PubMed ID: 15625000
Date Deposited: 07 Aug 2013 15:09
Last Modified: 02 Feb 2019 15:58


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