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Synthesis of functionalized isoindolinones: Addition of in situ generated organoalanes to acyliminium ions

Pierce, JG and Waller, DL and Wipf, P (2007) Synthesis of functionalized isoindolinones: Addition of in situ generated organoalanes to acyliminium ions. Journal of Organometallic Chemistry, 692 (21). 4618 - 4629. ISSN 0022-328X

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Abstract

Addition of in situ generated di- or trisubstituted alkenylalanes to N-acyliminium ions provides rapid access to functionalized isoindolinones. Subsequent ring closing metathesis leads to tricyclic products. These transformations proceed under mild conditions and allow for the convergent synthesis of biologically significant scaffolds from readily available starting materials.{A figure is presented}. © 2007 Elsevier B.V. All rights reserved.

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Details

Item Type: Article
Status: Published
Creators/Authors:
CreatorsEmailPitt UsernameORCID
Pierce, JG
Waller, DL
Wipf, Ppwipf@pitt.eduPWIPF
Date: 1 October 2007
Date Type: Publication
Journal or Publication Title: Journal of Organometallic Chemistry
Volume: 692
Number: 21
Page Range: 4618 - 4629
DOI or Unique Handle: 10.1016/j.jorganchem.2007.05.035
Schools and Programs: Dietrich School of Arts and Sciences > Chemistry
Refereed: Yes
ISSN: 0022-328X
PubMed Central ID: PMC2726970
PubMed ID: 19684878
Date Deposited: 09 Oct 2013 16:03
Last Modified: 13 Oct 2017 17:55
URI: http://d-scholarship.pitt.edu/id/eprint/19807

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