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Extractive phase vanishing reactions with dichloromethane, perfluorohexanes, and dibromoethane: Slow addition in a test tube

Curran, DP and Werner, S (2004) Extractive phase vanishing reactions with dichloromethane, perfluorohexanes, and dibromoethane: Slow addition in a test tube. Organic Letters, 6 (6). 1021 - 1024. ISSN 1523-7060

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Abstract

(Equation presented) Partition coefficient measurements and experiments with a dye show that a new fluorous "phase vanishing reaction" described by Jana and Verkade occurs by an extractive mechanism. This mechanism is contrasted with the original diffusive phase-vanishing reactions introduced by Ryu and co-workers.


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Details

Item Type: Article
Status: Published
Creators/Authors:
CreatorsEmailPitt UsernameORCID
Curran, DPcurran@pitt.eduCURRAN
Werner, S
Date: 18 March 2004
Date Type: Publication
Journal or Publication Title: Organic Letters
Volume: 6
Number: 6
Page Range: 1021 - 1024
DOI or Unique Handle: 10.1021/ol0499248
Schools and Programs: Dietrich School of Arts and Sciences > Chemistry
Refereed: Yes
ISSN: 1523-7060
MeSH Headings: Azo Compounds; Countercurrent Distribution; Diffusion; Ethylene Dibromide--chemistry; Fluorocarbons--chemistry; Indicators and Reagents; Methylene Chloride--chemistry; Solvents--chemistry; Time Factors
PubMed ID: 15012090
Date Deposited: 30 Oct 2013 16:59
Last Modified: 02 Feb 2019 15:58
URI: http://d-scholarship.pitt.edu/id/eprint/19909

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