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Fluorous dienophiles are powerful diene scavengers in diels-alder reactions

Werner, S and Curran, DP (2003) Fluorous dienophiles are powerful diene scavengers in diels-alder reactions. Organic Letters, 5 (18). 3293 - 3296. ISSN 1523-7060

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(Matrix presented) Three fluorous dienophiles have been synthesized, and their value in scavenging an excess diene after Diels-Alder reactions is shown. The resulting fluorous derivatives are separated by solid-phase extraction on fluorous silica gel (FSPE). The fluorous [1,2,4]triazoline-3,5-dione 10 reacted with most dienes within seconds or minutes.


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Item Type: Article
Status: Published
CreatorsEmailPitt UsernameORCID
Werner, S
Curran, DPcurran@pitt.eduCURRAN
Date: 4 September 2003
Date Type: Publication
Journal or Publication Title: Organic Letters
Volume: 5
Number: 18
Page Range: 3293 - 3296
DOI or Unique Handle: 10.1021/ol035214a
Schools and Programs: Dietrich School of Arts and Sciences > Chemistry
Refereed: Yes
ISSN: 1523-7060
MeSH Headings: Aldehydes--chemistry; Alkenes--chemical synthesis; Amines--chemistry; Catalysis; Fluorine--chemistry; Maleimides--chemistry; Molecular Structure; Stereoisomerism; Triazoles--chemistry
PubMed ID: 12943410
Date Deposited: 30 Oct 2013 16:48
Last Modified: 02 Feb 2019 15:58


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