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Stereochemistry of oxachlorocarbene S<inf>N</inf>i reactions

Moss, RA and Fu, X and Tian, J and Sauers, R and Wipf, P (2005) Stereochemistry of oxachlorocarbene S<inf>N</inf>i reactions. Organic Letters, 7 (7). 1371 - 1374. ISSN 1523-7060

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Abstract

(Chemical Equation Presented) 3-Nortricyclyloxychlorocarbene and trans-4-methylcyclohexyloxychlorocarbene both fragment in hydrocarbon solvents with extensive loss of stereochemical integrity to the corresponding chlorides via competitive and nearly isoenergetic SNi-like transition states. © 2005 American Chemical Society.


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Details

Item Type: Article
Status: Published
Creators/Authors:
CreatorsEmailPitt UsernameORCID
Moss, RA
Fu, X
Tian, J
Sauers, R
Wipf, Ppwipf@pitt.eduPWIPF
Date: 31 March 2005
Date Type: Publication
Journal or Publication Title: Organic Letters
Volume: 7
Number: 7
Page Range: 1371 - 1374
DOI or Unique Handle: 10.1021/ol050185k
Schools and Programs: Dietrich School of Arts and Sciences > Chemistry
Refereed: Yes
ISSN: 1523-7060
PubMed ID: 15787509
Date Deposited: 12 Nov 2013 17:17
Last Modified: 02 Feb 2019 15:56
URI: http://d-scholarship.pitt.edu/id/eprint/19981

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