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Three-component synthesis of α,β-cyclopropyl-γ-amino acids

Wipf, P and Stephenson, CRJ (2005) Three-component synthesis of α,β-cyclopropyl-γ-amino acids. Organic Letters, 7 (6). 1137 - 1140. ISSN 1523-7060

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(Chemical Equation Presented) The multicomponent coupling of alkenylzirconocenes with N-diphenylphosphinoyl imines provides rapid access to functionalized C-cyclopropylalkylamides which have been readily transformed into α,β-cyclopropyl-γ-amino acids. These novel scaffolds are thus accessible in ca. 8 steps from commercially available alkynes. © 2005 American Chemical Society.


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Item Type: Article
Status: Published
CreatorsEmailPitt UsernameORCID
Wipf, Ppwipf@pitt.eduPWIPF
Stephenson, CRJ
Date: 17 March 2005
Date Type: Publication
Journal or Publication Title: Organic Letters
Volume: 7
Number: 6
Page Range: 1137 - 1140
DOI or Unique Handle: 10.1021/ol0501525
Schools and Programs: Dietrich School of Arts and Sciences > Chemistry
Refereed: Yes
ISSN: 1523-7060
MeSH Headings: Alkynes--chemistry; Amino Acids--chemical synthesis; Amino Acids--chemistry; Catalysis; Cyclopropanes--chemical synthesis; Cyclopropanes--chemistry; Molecular Structure; Stereoisomerism
PubMed ID: 15760158
Date Deposited: 17 Dec 2013 15:29
Last Modified: 02 Feb 2019 15:57


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