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Synthesis of highly oxygenated dinaphthyl ethers via S<inf>N</inf>Ar reactions promoted by Barton's base

Wipf, P and Lynch, SM (2003) Synthesis of highly oxygenated dinaphthyl ethers via S<inf>N</inf>Ar reactions promoted by Barton's base. Organic Letters, 5 (7). 1155 - 1158. ISSN 1523-7060

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Abstract

(Matrix presented) Electron-rich dinaphthyl ethers were synthesized by SNAr reactions between naphthols and activated fluoronaphthalenes. 2-tert-Butyl-1,1,3,3-tetramethylguanidine (Barton's base) was found to be an excellent, mild alternative to traditional inorganic bases for promoting the coupling reaction.


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Details

Item Type: Article
Status: Published
Creators/Authors:
CreatorsEmailPitt UsernameORCID
Wipf, Ppwipf@pitt.eduPWIPF
Lynch, SM
Date: 3 April 2003
Date Type: Publication
Journal or Publication Title: Organic Letters
Volume: 5
Number: 7
Page Range: 1155 - 1158
DOI or Unique Handle: 10.1021/ol034286z
Schools and Programs: Dietrich School of Arts and Sciences > Chemistry
Refereed: Yes
ISSN: 1523-7060
MeSH Headings: Ethers--chemical synthesis; Ethers--chemistry; Guanidine--analogs & derivatives; Guanidine--chemistry; Heterocyclic Compounds with 4 or More Rings--chemical synthesis; Molecular Structure; Naphthalenes--chemistry; Naphthols--chemistry; Oxygen--chemistry; Spiro Compounds
PubMed ID: 12659597
Date Deposited: 31 Jan 2014 21:07
Last Modified: 02 Feb 2019 15:56
URI: http://d-scholarship.pitt.edu/id/eprint/20439

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