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Novel applications of alkenyl zirconocenes.

Wipf, Peter and Kendall, Christopher (2002) Novel applications of alkenyl zirconocenes. Chemistry, 8 (8). 1778 - 1784. ISSN 0947-6539

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Abstract

Alkenyl zirconocene complexes are readily obtained by diverse processes including hydrozirconation, carbozirconation, and cyclozirconation of alkynes, transmetalations, and bond insertions. In combination with other metals, novel reaction manifolds can emerge and provide access to useful synthetic building blocks. Both catalytic asymmetric processes and highly diastereoselective multicomponent transformations that involve the formation of three or more new carbon-carbon bonds are feasible. This Concept paper summarizes the current state of the art and opportunities for future reaction discovery in this field of research, with particular emphasis on synergistic effects of bimetallic combinations of zirconocenes and zinc.


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Details

Item Type: Article
Status: Published
Creators/Authors:
CreatorsEmailPitt UsernameORCID
Wipf, Peterpwipf@pitt.eduPWIPF
Kendall, Christopher
Date: 15 April 2002
Date Type: Publication
Journal or Publication Title: Chemistry
Volume: 8
Number: 8
Page Range: 1778 - 1784
DOI or Unique Handle: 10.1002/1521-3765(20020415)8:8<1778::aid-chem1778>3.0.co;2-h
Schools and Programs: Dietrich School of Arts and Sciences > Chemistry
Refereed: Yes
ISSN: 0947-6539
PubMed ID: 11933105
Date Deposited: 06 Feb 2014 23:58
Last Modified: 01 Oct 2019 23:55
URI: http://d-scholarship.pitt.edu/id/eprint/20450

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