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A New Ligand Scaffold for Catalytic Asymmetric Alkylzinc Additions to Aldehydes

Wipf, P and Wang, X (2002) A New Ligand Scaffold for Catalytic Asymmetric Alkylzinc Additions to Aldehydes. Organic Letters, 4 (7). 1197 - 1199. ISSN 1523-7060

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matrix presented 1,3-Azole derivatives of 2-aminocyclohexanecarboxylic acid represent a new class of bidentate ligands for metal-mediated catalytic asymmetric synthesis. N-[2-(4-Isopropyl-4,5-dihydrooxazol-2-yl)cyclohexyl]methanesulfonamide (6) is particularly well suited for the addition of alkylzinc reagents to aliphatic aldehydes in high enantiomeric excess.


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Item Type: Article
Status: Published
CreatorsEmailPitt UsernameORCID
Wipf, Ppwipf@pitt.eduPWIPF
Wang, X
Date: 4 April 2002
Date Type: Publication
Journal or Publication Title: Organic Letters
Volume: 4
Number: 7
Page Range: 1197 - 1199
DOI or Unique Handle: 10.1021/ol025600c
Schools and Programs: Dietrich School of Arts and Sciences > Chemistry
Refereed: Yes
ISSN: 1523-7060
Other ID: 10.1021/ol025600c
PubMed ID: 11922817
Date Deposited: 12 Feb 2014 23:42
Last Modified: 05 Feb 2019 16:55


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