Fluorous solvent as a new phase-screen medium between reagents and reactants in the bromination and chlorination of alcohols

Nakamura, H and Usui, T and Kuroda, H and Ryu, I and Matsubara, H and Yasuda, S and Curran, DP (2003) Fluorous solvent as a new phase-screen medium between reagents and reactants in the bromination and chlorination of alcohols. Organic Letters, 5 (8). 1167 - 1169. ISSN 1523-7060

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Abstract

(Matrix presented) A perfluorohexane layer regulates the rate of reagent transport in the bromination and chlorination of alcohols. A fluorous triphasic U-tube method is effective for lighter reagents; the thionyl chloride layer (yellow) vanishes, and the chlorides are obtained from the right top organic layer in the chlorination of alcohols.

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Details

Item Type:	Article
Status:	Published
Creators/Authors:	Creators Email Pitt Username ORCID Nakamura, H Usui, T Kuroda, H Ryu, I Matsubara, H Yasuda, S Curran, DP curran@pitt.edu CURRAN
Date:	17 April 2003
Date Type:	Publication
Journal or Publication Title:	Organic Letters
Volume:	5
Number:	8
Page Range:	1167 - 1169
DOI or Unique Handle:	10.1021/ol034060w
Schools and Programs:	Dietrich School of Arts and Sciences > Chemistry
Refereed:	Yes
ISSN:	1523-7060
PubMed ID:	12688710
Date Deposited:	06 Feb 2014 23:59
Last Modified:	02 Feb 2019 15:58
URI:	http://d-scholarship.pitt.edu/id/eprint/20464

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