N-Allylation of anilides with chiral palladium catalysts: The first catalytic asymmetric synthesis of axially chiral anilides

Terauchi, J and Curran, DP (2003) N-Allylation of anilides with chiral palladium catalysts: The first catalytic asymmetric synthesis of axially chiral anilides. Tetrahedron Asymmetry, 14 (5). 587 - 592. ISSN 0957-4166

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Abstract

The first catalytic asymmetric synthesis of axially chiral anilides has been carried out under palladium-catalyzed allylation reaction conditions with chiral phosphine ligands. Allylation of anilides bearing an ortho tert-butyl group with a palladium catalyst and (S)-BINAP as a chiral ligand gave axially chiral anilides in about 50% ee. © 2003 Elsevier Science Ltd. All rights reserved.

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Details

Item Type:	Article
Status:	Published
Creators/Authors:	Creators Email Pitt Username ORCID Terauchi, J Curran, DP curran@pitt.edu CURRAN
Date:	7 March 2003
Date Type:	Publication
Journal or Publication Title:	Tetrahedron Asymmetry
Volume:	14
Number:	5
Page Range:	587 - 592
DOI or Unique Handle:	10.1016/s0957-4166(03)00041-7
Schools and Programs:	Dietrich School of Arts and Sciences > Chemistry
Refereed:	Yes
ISSN:	0957-4166
Date Deposited:	06 Feb 2014 23:57
Last Modified:	02 Feb 2019 15:58
URI:	http://d-scholarship.pitt.edu/id/eprint/20465

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