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Water-Accelerated Tandem Claisen Rearrangement-Catalytic Asymmetric Carboalumination

Wipf, P and Ribe, S (2001) Water-Accelerated Tandem Claisen Rearrangement-Catalytic Asymmetric Carboalumination. Organic Letters, 3 (10). 1503 - 1505. ISSN 1523-7060

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matrix presented The addition of stoichiometric quantities of water accelerates both the trimethylaluminum-mediated aromatic Claisen reaction and the chiral zirconocene-catalyzed asymmetric carboalumination of terminal alkenes. The two reactions occur in a tandem sequence resulting in the selective formation of two new C-C and one C-O bond after oxidative quench of the intermediate trialkylalane.


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Item Type: Article
Status: Published
CreatorsEmailPitt UsernameORCID
Wipf, Ppwipf@pitt.eduPWIPF
Ribe, S
Date: 17 May 2001
Date Type: Publication
Journal or Publication Title: Organic Letters
Volume: 3
Number: 10
Page Range: 1503 - 1505
DOI or Unique Handle: 10.1021/ol015816z
Schools and Programs: Dietrich School of Arts and Sciences > Chemistry
Refereed: Yes
ISSN: 1523-7060
PubMed ID: 11388852
Date Deposited: 13 Feb 2014 18:57
Last Modified: 02 Feb 2019 15:57


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