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Phase-vanishing reactions that use fluorous media as a phase screen. Facile, controlled bromination of alkenes by dibromine and dealkylation of aromatic ethers by boron tribromide

Ryu, I and Matsubara, H and Yasuda, S and Nakamura, H and Curran, DP (2002) Phase-vanishing reactions that use fluorous media as a phase screen. Facile, controlled bromination of alkenes by dibromine and dealkylation of aromatic ethers by boron tribromide. Journal of the American Chemical Society, 124 (44). 12946 - 12947. ISSN 0002-7863

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Abstract

In fluorous triphasic reactions, such as bromination of alkenes by dibromine and dealkylation of aromatic ethers by boron tribromide, the middle fluorous phase acts as a liquid membrane permitting passive transport of the reagents at the bottom to the top layer involving the substrates, thereby regulating the reactions. Copyright © 2002 American Chemical Society.


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Details

Item Type: Article
Status: Published
Creators/Authors:
CreatorsEmailPitt UsernameORCID
Ryu, I
Matsubara, H
Yasuda, S
Nakamura, H
Curran, DPcurran@pitt.eduCURRAN
Date: 6 November 2002
Date Type: Publication
Journal or Publication Title: Journal of the American Chemical Society
Volume: 124
Number: 44
Page Range: 12946 - 12947
DOI or Unique Handle: 10.1021/ja027965y
Schools and Programs: Dietrich School of Arts and Sciences > Chemistry
Refereed: Yes
ISSN: 0002-7863
MeSH Headings: Alkenes--chemistry; Alkylation; Boron Compounds--chemistry; Bromine--chemistry; Ethers--chemistry; Fluorocarbons--chemistry; Hydrocarbons, Brominated--chemical synthesis
PubMed ID: 12405811
Date Deposited: 07 Feb 2014 00:02
Last Modified: 02 Feb 2019 15:58
URI: http://d-scholarship.pitt.edu/id/eprint/20487

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