Link to the University of Pittsburgh Homepage
Link to the University Library System Homepage Link to the Contact Us Form

Synthesis and asymmetric hydrogermylation reactions of dithiogermanium hydrides derived from C2-symmetric dithiols

Curran, DP and Gualtieri, G (2001) Synthesis and asymmetric hydrogermylation reactions of dithiogermanium hydrides derived from C2-symmetric dithiols. Synlett (SPEC. ). 1038 - 1041. ISSN 0936-5214

[img] Plain Text (licence)
Available under License : See the attached license file.

Download (1kB)

Abstract

Two members of a new class of dithiogermanium hydrides have been prepared in racemic and enantiopure form. Reaction of 2,2′-dithiobinap and 3,3′-bis-trimethylsilyl-2,2′-dithiobinap with tBuGeCl3 followed by reduction provides the corresponding germanium hydrides. Hydrogermylation of methyl methacrylate occurs with low selectivity (<3/1) for the former substrate but high selectivity (>10/1) for the latter.


Share

Citation/Export:
Social Networking:
Share |

Details

Item Type: Article
Status: Published
Creators/Authors:
CreatorsEmailPitt UsernameORCID
Curran, DPcurran@pitt.eduCURRAN
Gualtieri, G
Date: 27 June 2001
Date Type: Publication
Journal or Publication Title: Synlett
Number: SPEC.
Page Range: 1038 - 1041
Schools and Programs: Dietrich School of Arts and Sciences > Chemistry
Refereed: Yes
ISSN: 0936-5214
Date Deposited: 13 Feb 2014 23:52
Last Modified: 23 Jun 2018 13:56
URI: http://d-scholarship.pitt.edu/id/eprint/20540

Metrics

Monthly Views for the past 3 years

Plum Analytics


Actions (login required)

View Item View Item