Curran, DP and Gualtieri, G
(2001)
Synthesis and asymmetric hydrogermylation reactions of dithiogermanium hydrides derived from C2-symmetric dithiols.
Synlett (SPEC. ).
1038 - 1041.
ISSN 0936-5214
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Abstract
Two members of a new class of dithiogermanium hydrides have been prepared in racemic and enantiopure form. Reaction of 2,2′-dithiobinap and 3,3′-bis-trimethylsilyl-2,2′-dithiobinap with tBuGeCl3 followed by reduction provides the corresponding germanium hydrides. Hydrogermylation of methyl methacrylate occurs with low selectivity (<3/1) for the former substrate but high selectivity (>10/1) for the latter.
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