Synthesis and asymmetric hydrogermylation reactions of dithiogermanium hydrides derived from C2-symmetric dithiols

Curran, DP and Gualtieri, G (2001) Synthesis and asymmetric hydrogermylation reactions of dithiogermanium hydrides derived from C2-symmetric dithiols. Synlett (SPEC. ). 1038 - 1041. ISSN 0936-5214

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Abstract

Two members of a new class of dithiogermanium hydrides have been prepared in racemic and enantiopure form. Reaction of 2,2′-dithiobinap and 3,3′-bis-trimethylsilyl-2,2′-dithiobinap with tBuGeCl3 followed by reduction provides the corresponding germanium hydrides. Hydrogermylation of methyl methacrylate occurs with low selectivity (<3/1) for the former substrate but high selectivity (>10/1) for the latter.

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Details

Item Type:	Article
Status:	Published
Creators/Authors:	Creators Email Pitt Username ORCID Curran, DP curran@pitt.edu CURRAN Gualtieri, G
Date:	1 January 2001
Date Type:	Publication
Journal or Publication Title:	Synlett
Number:	SPEC.
Page Range:	1038 - 1041
DOI or Unique Handle:	10.1055/s-2001-14655
Schools and Programs:	Dietrich School of Arts and Sciences > Chemistry
Refereed:	Yes
ISSN:	0936-5214
Date Deposited:	13 Feb 2014 23:52
Last Modified:	04 Dec 2022 03:55
URI:	http://d-scholarship.pitt.edu/id/eprint/20540

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