Water/MAO acceleration of the zirconocene-catalyzed asymmetric methylalumination of α-olefins

Wipf, P and Ribe, S (2000) Water/MAO acceleration of the zirconocene-catalyzed asymmetric methylalumination of α-olefins. Organic Letters, 2 (12). 1713 - 1716. ISSN 1523-7060

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Abstract

(matrix presented) The zirconocene-catalyzed enantioselective methylalumination of terminal alkenes is greatly accelerated in the presence of water. Terminal olefins that are inert under the standard conditions can be readily methylated in good yields and with good to high enantioselectivities. Furthermore, methylaluminoxane is also shown to accelerate the reaction, albeit at a lesser rate.

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Details

Item Type:	Article
Status:	Published
Creators/Authors:	Creators Email Pitt Username ORCID Wipf, P pwipf@pitt.edu PWIPF Ribe, S
Date:	15 June 2000
Date Type:	Publication
Journal or Publication Title:	Organic Letters
Volume:	2
Number:	12
Page Range:	1713 - 1716
DOI or Unique Handle:	10.1021/ol005865w
Schools and Programs:	Dietrich School of Arts and Sciences > Chemistry
Refereed:	Yes
ISSN:	1523-7060
PubMed ID:	10880208
Date Deposited:	21 Feb 2014 21:09
Last Modified:	02 Feb 2019 15:56
URI:	http://d-scholarship.pitt.edu/id/eprint/20545

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