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Synthesis of perfluorinated allylic compounds by radical allylation and their purification over fluorous reverse-phase silica

Ryu, I and Kreimerman, S and Niguma, T and Minakata, S and Komatsu, M and Luo, Z and Curran, DP (2001) Synthesis of perfluorinated allylic compounds by radical allylation and their purification over fluorous reverse-phase silica. Tetrahedron Letters, 42 (5). 947 - 950. ISSN 0040-4039

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Abstract

A simple free-radical method for the preparation of a variety of perfluorinated allylic compounds has been developed starting from perfluoroalkyl iodides and allyltins. Allyltributyltin, methallyltributyltin and crotyltributyltin all proved to be useful for the transformation. The desired perfluorinated allylic compound was conveniently isolated from the crude mixture by solid-phase extraction with fluorous reverse-phase silica (FRPS). © 2001 Elsevier Science Ltd.


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Details

Item Type: Article
Status: Published
Creators/Authors:
CreatorsEmailPitt UsernameORCID
Ryu, I
Kreimerman, S
Niguma, T
Minakata, S
Komatsu, M
Luo, Z
Curran, DPcurran@pitt.eduCURRAN
Date: 29 January 2001
Date Type: Publication
Journal or Publication Title: Tetrahedron Letters
Volume: 42
Number: 5
Page Range: 947 - 950
DOI or Unique Handle: 10.1016/s0040-4039(00)02153-5
Schools and Programs: Dietrich School of Arts and Sciences > Chemistry
Refereed: Yes
ISSN: 0040-4039
Date Deposited: 14 Feb 2014 17:00
Last Modified: 02 Feb 2019 15:58
URI: http://d-scholarship.pitt.edu/id/eprint/20561

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