Buric, MP and Chen, KP and Falk, J and Woodruff, SD
(2009)
Improved sensitivity gas detection by spontaneous Raman scattering.
Applied Optics, 48 (22).
4424 - 4429.
ISSN 1559-128X
Abstract
Accurate, real-time measurement of the dilute constituents of a gaseous mixture poses a significant challenge usually relegated to mass spectrometry. Here, spontaneous Raman backscattering is used to detect low pressure molecular gases. Rapid detection of gases in the ∼100 parts in 106 (ppm) range is described. Improved sensitivity is brought about by use of a hollow-core, photonic bandgap fiber gas cell in the back-scattering configuration to increase collection efficiency and an image-plane aperture to greatly reduce silica-Raman background noise. Spatial and spectral properties of the silica noise were examined with a two-dimensional CCD detector array. © 2009 Optical Society of America.
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