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Formation of cyclopropanes by homolytic substitution reactions of 3- iodopropyl radicals: Preparative and rate studies

Curran, DP and Gabarda, AE (1999) Formation of cyclopropanes by homolytic substitution reactions of 3- iodopropyl radicals: Preparative and rate studies. Tetrahedron, 55 (11). 3327 - 3336. ISSN 0040-4020

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Abstract

Reduction of 2-substituted 1,3-diiodopropane derivatives with tin hydride provides substituted cyclopropanes. The reaction occurs through a homolytic substitution of the 3-iodopropyl radical, which has a rate constant of about 5 x 105 s-1 at 80°C.


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Details

Item Type: Article
Status: Published
Creators/Authors:
CreatorsEmailPitt UsernameORCID
Curran, DPcurran@pitt.eduCURRAN
Gabarda, AE
Date: 1 March 1999
Date Type: Publication
Journal or Publication Title: Tetrahedron
Volume: 55
Number: 11
Page Range: 3327 - 3336
DOI or Unique Handle: 10.1016/s0040-4020(98)01144-2
Schools and Programs: Dietrich School of Arts and Sciences > Chemistry
Refereed: Yes
ISSN: 0040-4020
Date Deposited: 22 Sep 2014 20:31
Last Modified: 02 Feb 2019 15:58
URI: http://d-scholarship.pitt.edu/id/eprint/22458

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