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'Propylene spaced' allyl tin reagents: A new class of fluorous tin reagents for allylations under radical and metal-catalyzed conditions

Curran, DP and Luo, Z and Degenkolb, P (1998) 'Propylene spaced' allyl tin reagents: A new class of fluorous tin reagents for allylations under radical and metal-catalyzed conditions. Bioorganic and Medicinal Chemistry Letters, 8 (17). 2403 - 2408. ISSN 0960-894X

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Abstract

A new generation of propylene-spaced fluorous allyltin reagents [(Rf(CH2)3)3SnCH2CH=CH2] is described. These succeed in radical allylations where their lower homologs (ethylene-spaced) fail, and they provide improved performance in transition metal catalyzed allylations. The reagents and byproducts are readily separated by simple fluorous-organic liquid-liquid or solid-liquid extractions.


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Details

Item Type: Article
Status: Published
Creators/Authors:
CreatorsEmailPitt UsernameORCID
Curran, DPcurran@pitt.eduCURRAN
Luo, Z
Degenkolb, P
Date: 8 September 1998
Date Type: Publication
Journal or Publication Title: Bioorganic and Medicinal Chemistry Letters
Volume: 8
Number: 17
Page Range: 2403 - 2408
DOI or Unique Handle: 10.1016/s0960-894x(98)00435-1
Schools and Programs: Dietrich School of Arts and Sciences > Chemistry
Refereed: Yes
ISSN: 0960-894X
MeSH Headings: Aldehydes--chemical synthesis; Aldehydes--chemistry; Alkenes; Catalysis; Fluorides; Indicators and Reagents; Metals; Organotin Compounds--chemical synthesis; Organotin Compounds--chemistry; Structure-Activity Relationship
PubMed ID: 9873550
Date Deposited: 28 Jul 2014 19:11
Last Modified: 02 Feb 2019 15:58
URI: http://d-scholarship.pitt.edu/id/eprint/22506

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