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Radical cyclization/fragmentation reactions of dicyanocyclopropanes to enaminonitriles. A radical alternative to the Thorpe-Ziegler reaction

Curran, DP and Liu, W (1999) Radical cyclization/fragmentation reactions of dicyanocyclopropanes to enaminonitriles. A radical alternative to the Thorpe-Ziegler reaction. Synlett (1). 117 - 119. ISSN 0936-5214

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Abstract

Radical cyclizations to dicyanocyclopropanes provide cyclic enaminonitriles by a series of radical reactions that features radical cyclization to a nitrile and cyclopropane cleavage. The direction of cyclopropane cleavage - and hence the ring size of the final product - depends on the nature of the ring formed in the initial cyclization to the nitrile.


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Details

Item Type: Article
Status: Published
Creators/Authors:
CreatorsEmailPitt UsernameORCID
Curran, DPcurran@pitt.eduCURRAN
Liu, W
Date: 1 January 1999
Date Type: Publication
Journal or Publication Title: Synlett
Number: 1
Page Range: 117 - 119
DOI or Unique Handle: 10.1055/s-1999-2551
Schools and Programs: Dietrich School of Arts and Sciences > Chemistry
Refereed: Yes
ISSN: 0936-5214
Date Deposited: 05 Aug 2014 21:31
Last Modified: 02 Feb 2019 15:58
URI: http://d-scholarship.pitt.edu/id/eprint/22621

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