Silver(I)-catalyzed addition of zirconocenes to epoxy esters: A new entry to 1,4-dicarbonyl compounds and pyridazinones

Wipf, P and Methot, JL (1999) Silver(I)-catalyzed addition of zirconocenes to epoxy esters: A new entry to 1,4-dicarbonyl compounds and pyridazinones. Organic Letters, 1 (8). 1253 - 1255. ISSN 1523-7060

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Abstract

(matrix presented) The Ag(I)-catalyzed tandem epoxy ester rearrangement-dioxycarbenium ion addition reaction with alkenyl zirconocenes provides 1,4-keto esters that can be further converted to substituted pyridazinones. The use of a fluorous tag in a cyclization-assisted cleavage strategy demonstrates the feasibility of extending this methodology to high-throughput organic synthesis.

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Details

Item Type:	Article
Status:	Published
Creators/Authors:	Creators Email Pitt Username ORCID Wipf, P pwipf@pitt.edu PWIPF Methot, JL
Date:	21 October 1999
Date Type:	Publication
Journal or Publication Title:	Organic Letters
Volume:	1
Number:	8
Page Range:	1253 - 1255
DOI or Unique Handle:	10.1021/ol990924v
Schools and Programs:	Dietrich School of Arts and Sciences > Chemistry
Refereed:	Yes
ISSN:	1523-7060
Date Deposited:	22 Jul 2015 14:25
Last Modified:	02 Feb 2019 15:57
URI:	http://d-scholarship.pitt.edu/id/eprint/25373

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