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Synthesis and Reactivity of Dioxycarbenium Ions from Epoxy Esters and Cationic Zirconium Complexes

Wipf, P and Xu, W (1993) Synthesis and Reactivity of Dioxycarbenium Ions from Epoxy Esters and Cationic Zirconium Complexes. Journal of Organic Chemistry, 58 (22). 5880 - 5882. ISSN 0022-3263

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Abstract

Rearrangement of epoxy esters in the presence of Cp 2 Zr(R) + or Cp 2 Zr(Cl) + results in synthetically useful dioxycarbenium intermediates. Acetals, ortho esters, and tetrahydrofurans are prepared by ligand transfer from zirconium, intramolecular trapping, or further rearrangement reactions. © 1993, American Chemical Society. All rights reserved.


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Details

Item Type: Article
Status: Published
Creators/Authors:
CreatorsEmailPitt UsernameORCID
Wipf, Ppwipf@pitt.eduPWIPF
Xu, W
Date: 1 January 1993
Date Type: Publication
Journal or Publication Title: Journal of Organic Chemistry
Volume: 58
Number: 22
Page Range: 5880 - 5882
DOI or Unique Handle: 10.1021/jo00074a006
Schools and Programs: Dietrich School of Arts and Sciences > Chemistry
Refereed: Yes
ISSN: 0022-3263
Date Deposited: 06 Oct 2015 14:56
Last Modified: 27 Apr 2019 14:55
URI: http://d-scholarship.pitt.edu/id/eprint/25724

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