Phenyl hydrazine as initiator for direct arene C-H arylation via base promoted homolytic aromatic substitution

Dewanji, A and Murarka, S and Curran, DP and Studer, A (2013) Phenyl hydrazine as initiator for direct arene C-H arylation via base promoted homolytic aromatic substitution. Organic Letters, 15 (23). 6102 - 6105. ISSN 1523-7060

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Abstract

A simple and efficient direct radical arylation of unactivated arenes is described which uses cheap and commercially available phenyl hydrazine as an initiator. The reaction occurs through a base promoted homolytic aromatic substitution (BHAS) mechanism involving aryl radicals and aryl radical anions as intermediates and offers a practical approach for preparation of an array of substituted biaryls. © 2013 American Chemical Society.

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Details

Item Type:	Article
Status:	Published
Creators/Authors:	Creators Email Pitt Username ORCID Dewanji, A Murarka, S Curran, DP curran@pitt.edu CURRAN Studer, A
Date:	6 December 2013
Date Type:	Publication
Journal or Publication Title:	Organic Letters
Volume:	15
Number:	23
Page Range:	6102 - 6105
DOI or Unique Handle:	10.1021/ol402995e
Schools and Programs:	Dietrich School of Arts and Sciences > Chemistry
Refereed:	Yes
ISSN:	1523-7060
MeSH Headings:	Benzene Derivatives--chemistry; Biphenyl Compounds--chemical synthesis; Biphenyl Compounds--chemistry; Catalysis; Molecular Structure; Phenylhydrazines--chemistry
Other ID:	NLM NIHMS542607, NLM PMC3946564
PubMed Central ID:	PMC3946564
PubMed ID:	24251964
Date Deposited:	10 Mar 2016 19:53
Last Modified:	02 Feb 2019 15:58
URI:	http://d-scholarship.pitt.edu/id/eprint/27206

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