Prokofjevs, A and Kampf, JW and Solovyev, A and Curran, DP and Vedejs, E
(2013)
Weakly stabilized primary borenium cations and their dicationic dimers.
Journal of the American Chemical Society, 135 (42).
15686 - 15689.
ISSN 0002-7863
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Abstract
Hydride abstraction from monocationic hydride bridged salts [H(H 2B-L)2]+ [B(C6F5) 4]̄ (L = Lewis base) generates an observable primary borenium cation for L = iPr2NEt, but with L = Me3N, Me 2NPr, or several N-heterocyclic carbenes, highly reactive dicationic dimers are formed. © 2013 American Chemical Society.
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Details
Item Type: |
Article
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Status: |
Published |
Creators/Authors: |
Creators | Email | Pitt Username | ORCID  |
---|
Prokofjevs, A | | | | Kampf, JW | | | | Solovyev, A | | | | Curran, DP | curran@pitt.edu | CURRAN | | Vedejs, E | | | |
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Date: |
23 October 2013 |
Date Type: |
Publication |
Journal or Publication Title: |
Journal of the American Chemical Society |
Volume: |
135 |
Number: |
42 |
Page Range: |
15686 - 15689 |
DOI or Unique Handle: |
10.1021/ja407458k |
Schools and Programs: |
Dietrich School of Arts and Sciences > Chemistry |
Refereed: |
Yes |
ISSN: |
0002-7863 |
MeSH Headings: |
Boron Compounds--chemical synthesis; Boron Compounds--chemistry; Cations--chemical synthesis; Cations--chemistry; Dimerization; Models, Molecular; Molecular Structure |
Other ID: |
NLM NIHMS531362, NLM PMC3857331 |
PubMed Central ID: |
PMC3857331 |
PubMed ID: |
24087933 |
Date Deposited: |
05 Apr 2016 14:30 |
Last Modified: |
22 Jun 2021 12:56 |
URI: |
http://d-scholarship.pitt.edu/id/eprint/27581 |
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