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Weakly stabilized primary borenium cations and their dicationic dimers

Prokofjevs, A and Kampf, JW and Solovyev, A and Curran, DP and Vedejs, E (2013) Weakly stabilized primary borenium cations and their dicationic dimers. Journal of the American Chemical Society, 135 (42). 15686 - 15689. ISSN 0002-7863

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Abstract

Hydride abstraction from monocationic hydride bridged salts [H(H 2B-L)2]+ [B(C6F5) 4]̄ (L = Lewis base) generates an observable primary borenium cation for L = iPr2NEt, but with L = Me3N, Me 2NPr, or several N-heterocyclic carbenes, highly reactive dicationic dimers are formed. © 2013 American Chemical Society.


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Details

Item Type: Article
Status: Published
Creators/Authors:
CreatorsEmailPitt UsernameORCID
Prokofjevs, A
Kampf, JW
Solovyev, A
Curran, DPcurran@pitt.eduCURRAN
Vedejs, E
Date: 1 January 2013
Date Type: Publication
Journal or Publication Title: Journal of the American Chemical Society
Volume: 135
Number: 42
Page Range: 15686 - 15689
DOI or Unique Handle: 10.1021/ja407458k
Schools and Programs: Dietrich School of Arts and Sciences > Chemistry
Refereed: Yes
ISSN: 0002-7863
MeSH Headings: Boron Compounds--chemical synthesis; Boron Compounds--chemistry; Cations--chemical synthesis; Cations--chemistry; Dimerization; Models, Molecular; Molecular Structure
Other ID: NLM NIHMS531362, NLM PMC3857331
PubMed Central ID: PMC3857331
PubMed ID: 24087933
Date Deposited: 05 Apr 2016 14:30
Last Modified: 02 Feb 2019 15:58
URI: http://d-scholarship.pitt.edu/id/eprint/27581

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