Weakly stabilized primary borenium cations and their dicationic dimers

Prokofjevs, A and Kampf, JW and Solovyev, A and Curran, DP and Vedejs, E (2013) Weakly stabilized primary borenium cations and their dicationic dimers. Journal of the American Chemical Society, 135 (42). 15686 - 15689. ISSN 0002-7863

Plain Text (licence) Available under License : See the attached license file. Download (1kB)

Abstract

Hydride abstraction from monocationic hydride bridged salts [H(H 2B-L)2]+ [B(C6F5) 4]̄ (L = Lewis base) generates an observable primary borenium cation for L = iPr2NEt, but with L = Me3N, Me 2NPr, or several N-heterocyclic carbenes, highly reactive dicationic dimers are formed. © 2013 American Chemical Society.

---

Share

Citation/Export:	Select format... Citation - Text Citation - HTML Endnote BibTex Dublin Core OpenURL MARC (ISO 2709) METS MODS EP3 XML Reference Manager Refer
Social Networking:	Share |

---

Details

Item Type:	Article
Status:	Published
Creators/Authors:	Creators Email Pitt Username ORCID Prokofjevs, A Kampf, JW Solovyev, A Curran, DP curran@pitt.edu CURRAN Vedejs, E
Date:	23 October 2013
Date Type:	Publication
Journal or Publication Title:	Journal of the American Chemical Society
Volume:	135
Number:	42
Page Range:	15686 - 15689
DOI or Unique Handle:	10.1021/ja407458k
Schools and Programs:	Dietrich School of Arts and Sciences > Chemistry
Refereed:	Yes
ISSN:	0002-7863
MeSH Headings:	Boron Compounds--chemical synthesis; Boron Compounds--chemistry; Cations--chemical synthesis; Cations--chemistry; Dimerization; Models, Molecular; Molecular Structure
Other ID:	NLM NIHMS531362, NLM PMC3857331
PubMed Central ID:	PMC3857331
PubMed ID:	24087933
Date Deposited:	05 Apr 2016 14:30
Last Modified:	22 Jun 2021 12:56
URI:	http://d-scholarship.pitt.edu/id/eprint/27581

---

Metrics

Monthly Views for the past 3 years

Plum Analytics

Altmetric.com

---

Actions (login required)

View Item