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Energy Level Structure of Free Excitons in 4H SiC from Wavelength Modulated Absorption Spectroscopy and Low Temperature Photoluminescence

Klahold, Walter (2018) Energy Level Structure of Free Excitons in 4H SiC from Wavelength Modulated Absorption Spectroscopy and Low Temperature Photoluminescence. Doctoral Dissertation, University of Pittsburgh. (Unpublished)

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Silicon carbide is a semiconductor material that holds special interest for its use in electronics meant to withstand harsh environments and demanding operating conditions. Its technological importance has been recognized over the course of a relatively long history of research and development, but only recently have growth and production capabilities allowed this material to become a viable platform for industrial electronics. To take advantage of these recent advancements, use is made of high quality 4H SiC boule and epitaxial samples to study the material’s photoluminescence and wavelength modulated absorption (WMA) spectra at 2 K or lower in temperature. The main results have been obtained in the WMA measurements, which have been performed in this work at higher resolution than in previous studies. In the wavelength region of interest here (∼3500–4000 ̊A), the dominant absorption and emission processes are characterized by excitation or recombination of free excitons whose electron and hole occupy the valence and conduction band extrema.
Four known features of the WMA spectrum have been found to reproducibly exhibit 0.7±0.1 meV splittings that have not been resolved previously. These have been observed for samples taken from two independently grown 4 cm diameter boules, and have the spectral profile characteristic of free exciton absorption. The multiplicity of these splittings for polarized illumination of the sample is consistent with a splitting of the free exciton ground state. Several other features which clearly do not have the shape expected for free exciton absorption will be shown to originate from an avoided crossing between the topmost valence bands. A preliminary examination of the WMA spectrum in the range ∼3500–3660 ̊A (∼3.4–3.6 eV) shows evidence of free exciton absorption processes due either to the exciton’s hole occupying a lower-lying valence band (separated from the topmost by the crystal field splitting) or the exciton’s electron occupying the second lowest conduction band minimum. The locations of these features in the absorption spectrum are consistent with the calculated
positions of these band extrema in the electronic band structure, for which there still remains little experimental evidence even today.


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Item Type: University of Pittsburgh ETD
Status: Unpublished
CreatorsEmailPitt UsernameORCID
Klahold, Walterwak19@pitt.eduwak190000-0001-7850-6667
ETD Committee:
TitleMemberEmail AddressPitt UsernameORCID
Committee ChairChoyke, Wolfgangchoyke@pitt.educhoyke
Committee CoChairDevaty, Robertdevaty@pitt.edudevaty
Committee MemberPaolone, Vittoriovipres@pitt.eduvipres
Committee MemberMong, Rogerrmong@pitt.edurmong
Committee MemberFeenstra,
Date: 28 June 2018
Date Type: Publication
Defense Date: 5 April 2018
Approval Date: 28 June 2018
Submission Date: 23 April 2018
Access Restriction: No restriction; Release the ETD for access worldwide immediately.
Number of Pages: 188
Institution: University of Pittsburgh
Schools and Programs: Dietrich School of Arts and Sciences > Physics
Degree: PhD - Doctor of Philosophy
Thesis Type: Doctoral Dissertation
Refereed: Yes
Uncontrolled Keywords: silicon carbide, 4H silicon carbide, free exciton, bound exciton, wavelength modulated absorption, photoluminescence, optical spectroscopy, band structure, spin-orbit splitting, crystal field splitting, nonparabolicity, mass anisotropy, exchange interaction, electron phonon interaction, electron photon interaction
Date Deposited: 28 Jun 2018 15:36
Last Modified: 28 Jun 2018 15:36


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