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Graphene Quantum Dots Doped PVDF(TBT)/PVP(TBT) Fiber Film with Enhanced Photocatalytic Performance

Zhang, Fubao and Yang, Chen and Wang, Xiao-Xiong and Li, Ru and Wan, Zhong and Wang, Xianming and Wan, Yong and Long, Yun-Ze and Cai, Zhongyu (2020) Graphene Quantum Dots Doped PVDF(TBT)/PVP(TBT) Fiber Film with Enhanced Photocatalytic Performance. Applied Sciences, 10 (2). p. 596. ISSN 2076-3417

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Abstract

We report the fabrication of polyvinylidene fluoride (tetrabutyl titanate)/polyvinyl pyrrolidone ((tetrabutyl titanate))-graphene quantum dots [PVDF(TBT)/PVP(TBT)-GQDs] film photocatalyst with enhanced photocatalytic performance. The polyvinylidene fluoride (tetrabutyl titanate)/polyvinyl pyrrolidone ((tetrabutyl titanate)) [PVDF(TBT)/PVP(TBT)] film was first prepared with a dual-electrospinning method and then followed by attaching graphene quantum dots (GQDs) to the surface of the composite film through a hydrothermal method. Later, part of the PVP in the composite film was dissolved by a hydrothermal method. As a result, a PVDF(TBT)/PVP(TBT)-GQDs film photocatalyst with a larger specific surface area was achieved. The photocatalytic degradation behavior of the PVDF(TBT)/PVP(TBT)-GQDs film photocatalyst was examined by using Rhodamine B as the target contaminant. The PVDF(TBT)/PVP(TBT)-GQDs photocatalyst showed a higher photocatalytic efficiency than PVDF(TBT)-H<sub>2</sub>O, PVDF(TBT)/PVP(TBT)-H<sub>2</sub>O, and PVDF(TBT)-GQDs, respectively. The enhanced photocatalytic efficiency can be attributed to the broader optical response range of the PVDF(TBT)/PVP(TBT)-GQDs photocatalyst, which makes it useful as an effective photocatalyst under white light irradiation.


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Details

Item Type: Article
Status: Published
Creators/Authors:
CreatorsEmailPitt UsernameORCID
Zhang, Fubao
Yang, Chen
Wang, Xiao-Xiong
Li, Ru
Wan, Zhong
Wang, Xianming
Wan, Yong
Long, Yun-Ze
Cai, Zhongyuzhc35@pitt.eduzhc35
Date: 14 January 2020
Date Type: Publication
Journal or Publication Title: Applied Sciences
Volume: 10
Number: 2
Publisher: MDPI AG
Page Range: p. 596
DOI or Unique Handle: 10.3390/app10020596
Schools and Programs: Dietrich School of Arts and Sciences > Chemistry
Refereed: Yes
Uncontrolled Keywords: electrospinning, nanofiber film, tetrabutyl titanate composites, graphene quantum dots, visible light photocatalysis
ISSN: 2076-3417
Official URL: http://dx.doi.org/10.3390/app10020596
Funders: National Natural Science Foundation of China, joint French-Singaporean MERLION program, Taishan Scholars Program of Shandong Province
Article Type: Research Article
Date Deposited: 19 May 2021 18:19
Last Modified: 19 May 2021 18:19
URI: http://d-scholarship.pitt.edu/id/eprint/41125

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