Meta, Christopher Todd
(2005)
Stereoselective Preparation of Highly Substituted Olefins and Synthetic Studies Toward Stresgenin B.
Master's Thesis, University of Pittsburgh.
(Unpublished)
Abstract
Alkenoic esters are versatile synthetic intermediates and are contained in many natural products. We have developed methods to stereoselectively prepare substituted alkenoic esters through the trans-conjugate addition of a nucleophile and an electrophile across the triple bond of γ-hydroxy-α,β-acetylenic esters. The development and scope of these methods will be discussed. Our preliminary studies toward the synthesis of stresgenin B are also described.
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Details
| Item Type: |
University of Pittsburgh ETD
|
| Status: |
Unpublished |
| Creators/Authors: |
|
| ETD Committee: |
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| Date: |
7 June 2005 |
| Date Type: |
Completion |
| Defense Date: |
10 December 2004 |
| Approval Date: |
7 June 2005 |
| Submission Date: |
21 April 2005 |
| Access Restriction: |
No restriction; Release the ETD for access worldwide immediately. |
| Institution: |
University of Pittsburgh |
| Schools and Programs: |
Dietrich School of Arts and Sciences > Chemistry |
| Degree: |
MS - Master of Science |
| Thesis Type: |
Master's Thesis |
| Refereed: |
Yes |
| Uncontrolled Keywords: |
diversity-oriented synthesis; natural product synthesis |
| Other ID: |
http://etd.library.pitt.edu/ETD/available/etd-04212005-195341/, etd-04212005-195341 |
| Date Deposited: |
10 Nov 2011 19:40 |
| Last Modified: |
15 Nov 2016 13:41 |
| URI: |
http://d-scholarship.pitt.edu/id/eprint/7413 |
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