Homoallylic amines by reductive inter- and intramolecular coupling of allenes and nitriles

Wipf, P and Manojlovic, MD (2011) Homoallylic amines by reductive inter- and intramolecular coupling of allenes and nitriles. Beilstein Journal of Organic Chemistry, 7. 824 - 830. ISSN 1860-5397

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Abstract

The one-pot hydrozirconation of allenes and nitriles followed by an in situ transmetalation of the allylzirconocene with dimethylzinc or zinc chloride provides functionalized homoallylic amines. An intramolecular version of this process leads to 3-aminotetrahydrofurans and 3-aminotetrahydropyrans. © 2011 Wipf and Manojlovic; licensee Beilstein-Institut.

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Details

Item Type:	Article
Status:	Published
Creators/Authors:	Creators Email Pitt Username ORCID Wipf, P pwipf@pitt.edu PWIPF Manojlovic, MD
Date:	17 June 2011
Date Type:	Publication
Journal or Publication Title:	Beilstein Journal of Organic Chemistry
Volume:	7
Page Range:	824 - 830
DOI or Unique Handle:	10.3762/bjoc.7.94
Schools and Programs:	Dietrich School of Arts and Sciences > Chemistry
Refereed:	Yes
ISSN:	1860-5397
Other ID:	NLM PMC3135093
PubMed Central ID:	PMC3135093
PubMed ID:	21804878
Date Deposited:	31 Jul 2014 20:47
Last Modified:	02 Feb 2019 15:57
URI:	http://d-scholarship.pitt.edu/id/eprint/22338

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