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DEVELOPMENT OF PHOTO-SENSITIZED PRECIPITONS AND STUDIES TOWARD THEIR USE AS LIGHT-ACTIVACTED, REVERSIBLE PHASE TAGS

Martucci, Michael Thomas (2009) DEVELOPMENT OF PHOTO-SENSITIZED PRECIPITONS AND STUDIES TOWARD THEIR USE AS LIGHT-ACTIVACTED, REVERSIBLE PHASE TAGS. Master's Thesis, University of Pittsburgh. (Unpublished)

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Abstract

This dissertation chronicles the discovery and development of an intermolecular photosensitized trans to cis isomerization protocol for bi-phenyl phenyl precipiton phase tags. The optimization of reaction and irradiation conditions, scale-up experiments and isomerization kinetics are presented. This class of precipiton can now be used as a dynamic reversible phase tag ideally suited for multi-step synthesis on multi-gram scale


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Details

Item Type: University of Pittsburgh ETD
Status: Unpublished
Creators/Authors:
CreatorsEmailPitt UsernameORCID
Martucci, Michael Thomasmobiusbelmont@gmail,com
ETD Committee:
TitleMemberEmail AddressPitt UsernameORCID
Committee ChairWilcox, Craig Sdaylite@pitt.eduDAYLITE
Committee MemberCurran, Dennis Pcurran@pitt.eduCURRAN
Committee MemberGrabowski, Joseph Jjoeg@pitt.eduJOEG
Date: 22 January 2009
Date Type: Completion
Defense Date: 13 November 2003
Approval Date: 22 January 2009
Submission Date: 4 August 2008
Access Restriction: 5 year -- Restrict access to University of Pittsburgh for a period of 5 years.
Institution: University of Pittsburgh
Schools and Programs: Dietrich School of Arts and Sciences > Chemistry
Degree: MS - Master of Science
Thesis Type: Master's Thesis
Refereed: Yes
Uncontrolled Keywords: organic synthesis; photosensitizer; precipiton; phase tag; separation
Other ID: http://etd.library.pitt.edu/ETD/available/etd-08042008-115807/, etd-08042008-115807
Date Deposited: 10 Nov 2011 19:57
Last Modified: 15 Nov 2016 13:48
URI: http://d-scholarship.pitt.edu/id/eprint/8881

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